P,S-Bidentate Phosphoramidites with (Ra)-BINOL Core in Palladium-Catalyzed Asymmetric Allylic Substitution
نویسندگان
چکیده
Abstract New P , S -bidentate phosphoramidite ligands, including these having a stereogenic phosphorus atom in the 1,3,2-dioxaphosphepine ring, have been synthesized on basis of ( R )-BINOL and its adamantanyl derivatives. With their participation Pd-catalyzed asymmetric allylic alkylation E )-1,3-diphenylallyl acetate with dimethyl malonate amination pyrrolidine involving ligands afforded selectivity up to 84 75% ee respectively.
منابع مشابه
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ژورنال
عنوان ژورنال: Russian Journal of General Chemistry
سال: 2022
ISSN: ['1070-3632', '1608-3350']
DOI: https://doi.org/10.1134/s1070363222120088